That answer (which you referred to) is not elaborate enough for it to be unusual to be posted by another user (i.e., other than the OP) within a minute or so of the question.
If an answer like this amazing one had been posted immediately on a question by an apparently different user, that would be strange. But even that would not necessarily be alarming: I know I've written material for Ask Ubuntu, realized it didn't fit for what I'd written it for, filed it away for later use, and posted it (with appropriate alteration/customization) on a newer question that it turned out to answer. I presume other users do that too, from time to time.
This sort of thing doesn't seem likely to me to relate to intentional misuse of the site. Question-answer pairs by a single author are encouraged, so there's little reason for someone to make a question and an answer using two separate accounts. Even if someone did so with the intention of concealing that they were the asker or answerer, it's not clear that would be considered abuse. The idea that a user's separate accounts should not interact is a very general one: really, it appears sockpuppetry (using multiple accounts to add weight to an opinion, attitude, or idea or to exercise disproportionately large social/political influence through misrepresentation), trolling, bullying, and spamming are the only uses of multiple accounts considered abusive.
You might find people asking and answering questions with different accounts as part of a larger pattern of irregularity. If that larger pattern included indications of misuse--like one account voting for another--then this would be an indication of a problem. But the mere fact that a question is answered quickly with more than a one or two sentence answer is not, in my opinion, something to be concerned about.
With that said, if you believe someone is abusing the site or hurting others on it, and you don't want to post on meta about it, you can raise a custom moderator flag to explain the problem. For a problem that is related to a post, there's a natural way to do this: just flag one of the posts that's involved (probably the answer) and explain your concerns.